Dr Andrew Phillips PhD
Contact Details
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Biography:
| Stokes Lecturer, Inorganic Chemistry (September 2008-Present). Fonctionnaire scientifique (January 2006-July 2008). European Commission Funded Post-doctoral Fellowship (May 2003-September 2005). Istituto di Chimica dei Composti Organo Metallici (ICCOM) at Consiglio Nazionale delle Ricerche (CNR), Sesto Fiorentino, Florence, Italy; (Drs. C. Bianchini, C. Mealli and M. Peruzzini). Universitat Autònoma de Barcelona, Bellaterra, Spain; (Dr. A. Lledós). Short term scientific exchange. Laboratoire de Chemie de Coordination at Centre National de La Recherche Scientifque (CNRS) Toulouse, France; (Drs. R. Poli and J.-C. Daran) Short term scientific exchange. Post-doctorial Fellowship (February 2001-April 2003). Doctor of Philosophy in Chemistry (July 1996-January 2001). Honours Bachelor in Science (September 1992-June 1996). |
Research Interests
| Metal based anticancer and antibacterial drugs. Catalysis with new strongly donating nitrogen ligands. Development of aqueous and biphasic catalytic systems. Synthesis and characterization of unusually bonded transition metal and main group complexes.
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Peer Reviewed Journals
Renfrew, A. K.,Phillips, A. D.,Egger, A. E.,Hartinger, C. G.,Bosquain, S. S.,Nazarov, A. A.,Keppler, B. K.,Gonsalvi, L.,Peruzzini, M.,Dyson, P. J.; (2009) 'Influence of Structural Variation on the Anticancer Activity of RAPTA-Type Complexes: ptn versus pta'. Organometallics, 28 (4):1165-1172.  [Details] |
| Yang, X.,Fei, Z. F.,Geldbach, T. J.,Phillips, A. D.,Hartinger, C. G.,Li, Y. D.,Dyson, P. J.; (2008) 'Suzuki coupling reactions in ether-functionalized ionic liquids: The importance of weakly interacting cations'. Organometallics, 27 (15):3971-3977. [Details] |
| Chaplin, A. B.,Beni, Z.,Hartinger, C. G.,Ben Hamidane, H.,Phillips, A. D.,Scopelliti, R.,Dyson, P. J.; (2008) 'Linked metal-cluster systems: Isolation and characterisation of {anti-[(p-cymene)RuCl]-mu-[kappa(2)-P,P ';kappa(1)-P ''-(PPh2CH2)(3)CMe]-[AuPt3(CO)(3)(PCy3)(3)]}(PF6)(2)'. Journal of Cluster Science, 19 (1):295-309. [Details] |
| Erlandsson, M.,Landaeta, V. R.,Gonsalvi, L.,Peruzzini, M.,Phillips, A. D.,Dyson, P. J.,Laurenczy, G.; (2008) '(Pentamethylcyclopentadienyl)iridium-PTA (PTA=1,3,5-triaza-7-phosphaadamantane) complexes and their application in catalytic water phase carbon dioxide hydrogenation'. European Journal of Inorganic Chemistry, (4):620-627. [Details] |
| Phillips, A. D.,Laurenczy, G.,Scopelliti, R.,Dyson, P. J.; (2007) 'Facile, thermoreversible cycloaddition of small molecules to a ruthenium(II) arene beta-diketiminate'. Organometallics, 26 (5):1120-1122. [Details] |
| Mealli, C.,Ienco, A.,Phillips, A. D.,Galindo, A.; (2007) 'A critical review of electronic effects in enediamido and alpha-dfimino complexes of the group 4 metals'. European Journal of Inorganic Chemistry, (18):2556-2568. [Details] |
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| Rossin, A.,Gonsalvi, L.,Phillips, A. D.,Maresca, O.,Lledos, A.,Peruzzini, M.; (2007) 'Water-assisted H-H bond splitting mediated by [CpRu(PTA)(2)Cl] (PTA=1,3,5-triaza-7-phosphaadamantane). A DFT analysis'. Organometallics, 26 (14):3289-3296. [Details] |
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| Vock, C. A.,Ang, W. H.,Scolaro, C.,Phillips, A. D.,Lagopoulos, L.,Juillerat-Jeanneret, L.,Sava, G.,Scopelliti, R.,Dyson, P. J.; (2007) 'Development of ruthenium antitumor drugs that overcome multidrug resistance mechanisms'. Journal of Medicinal Chemistry, 50 (9):2166-2175. [Details] |
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| Phillips, A. D.,Bolano, S.,Bosquain, S. S.,Daran, J. C.,Malacea, R.,Peruzzini, M.,Poli, R.,Gonsalvi, L.; (2006) 'A new class of rhodium(I) kappa(1)-P and kappa(2)-P,N complexes with rigid PTN(R) ligands (PTN=7-phospha-3-methyl-1,3,5-triazabicyclo[3.3.1]nonane)'. Organometallics, 25 (9):2189-2200. [Details] |
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| Vock, C. A.,Scolaro, C.,Phillips, A. D.,Scopelliti, R.,Sava, G.,Dyson, P. J.; (2006) 'Synthesis, characterization, and in vitro evaluation of novel ruthenium(II) eta(6)-arene imidazole complexes'. Journal of Medicinal Chemistry, 49 (18):5552-5561. [Details] |
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| Phillips, A. D.,Ienco, A.,Reinhold, J.,Bottcher, H. C.,Mealli, C.; (2006) 'A counterintuitive structural effect of metal-metal bond protonation and its electronic underpinnings'. Chemistry-a European Journal, 12 (17):4691-4701. [Details] |
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| Pattacini, R.,Predieri, G.,Tiripicchio, A.,Mealli, C.,Phillips, A. D.; (2006) 'Experimental and computational studies on the solvent-controlled cluster isomerism of Ru-3(H)(CO)(9)(NPPh3) and related dynamics'. Chemical Communications, (14):1527-1529. [Details] |
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| Dorcier, A.,Ang, W. H.,Bolano, S.,Gonsalvi, L.,Juillerat-Jeannerat, L.,Laurenczy, G.,Peruzzini, M.,Phillips, A. D.,Zanobini, F.,Dyson, P. J.; (2006) 'In vitro evaluation of rhodium and osmium RAPTA analogues: The case for organometallic anticancer drugs not based on ruthenium'. Organometallics, 25 (17):4090-4096. [Details] |
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| Wright, R. J.,Phillips, A. D.,Hino, S.,Power, P. P.; (2005) 'Synthesis and reactivity of dimeric Ar ' TITIAr ' and trimeric (Ar '' TI)(3) (Ar ', Ar ''= bulky terphenyl group) thallium(I) derivatives: TI(I)-TI(I) bonding in species ligated by monodentate ligands'. Journal of the American Chemical Society, 127 (13):4794-4799. [Details] |
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| Phillips, A. D.,Power, P. P.; (2005) 'A main-group donor-acceptor adduct: 1,3,4,5-tetramethylimidazol-2-yl-idene-tris(pentafluorophenyl)borane'. Acta Crystallographica Section C-Crystal Structure Communications, 61 :O291-O293. [Details] |
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| Burford, N.,Phillips, A. D.,Spinney, H. A.,Lumsden, M.,Werner-Zwanziger, U.,Ferguson, M. J.,McDonald, R.; (2005) 'Hypervalent, low-coordinate phosphorus(III) centers in complexes of the phosphadiazonium cation with chelate ligands'. Journal of the American Chemical Society, 127 (11):3921-3927. [Details] |
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| Burford, N.,Dyker, C. A.,Phillips, A. D.,Spinney, H. A.,Decken, A.,McDonald, R.,Ragogna, P. J.,Rheingold, A. L.; (2004) 'Ylidene -> iminophosphine coordination complexes and reversible dissociation of dichlorophosphetidines'. Inorganic Chemistry, 43 (23):7502-7507. [Details] |
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| Hino, S.,Olmstead, M.,Phillips, A. D.,Wright, R. J.,Power, P. P.; (2004) 'Terphenyl ligand stabilized lead(II) derivatives: Steric effects and lead-lead bonding in diplumbenes'. Inorganic Chemistry, 43 (23):7346-7352. [Details] |
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| Wright, R. J.,Phillips, A. D.,Hino, S.,Power, P. P.; (2004) 'Synthesis and solid state structures of (Ar'Tl)2 and (Ar"Tl)3: Dimeric and trimeric terphenyl thallium clusters'. Abstracts of Papers of the American Chemical Society, 227 :725-INOR. [Details] |
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| Phillips, A. D.,Gonsalvi, L.,Rornerosa, A.,Vizza, F.,Peruzzini, M.; (2004) 'Coordination chemistry of 1,3,5-triaza-7-phosphaadamantane (PTA) - Transition metal complexes and related catalytic, medicinal and photoluminescent applications'. Coordination Chemistry Reviews, 248 (11-12):955-993. [Details] |
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| Hino, S.,Brynda, M.,Phillips, A. D.,Power, P. P.; (2004) 'Synthesis and characterization of a quasi-one-coordinate lead cation'. Angewandte Chemie-International Edition, 43 (20):2655-2658. [Details] |
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| Eichler, B. E.,Phillips, A. D.,Power, P. P.; (2003) 'Reactions of phenyllithium with the stannylene Ar*SnPh (Ar* = C6H3-2,6-Trip(2); Trip = C6H2-2,4,6-Pr-3(i)) and the synthesis of the distannylstannylene Sn(SnPh2Ar*)(2): Contrasting behavior in methyl and phenyl derivatives'. Organometallics, 22 (26):5423-5426. [Details] |
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| Phillips, A. D.,Hino, S.,Power, P. P.; (2003) 'A reversible valence equilibrium in a heavier main group compound'. Journal of the American Chemical Society, 125 (25):7520-7521. [Details] |
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| Stanciu, C.,Olmstead, M. M.,Phillips, A. D.,Stender, M.,Power, P. P.; (2003) 'Synthesis and characterization of the very bulky phenols Ar*OH and Ar ' OH (Ar* = C6H3-2,6-Trip(2), Trip = C6H2-2,4,6-iPr(3); Ar ' = C6H3-2,6-Dipp(2), Dipp = C6H3-2,6-iPr(2)) and their lithium and sodium derivatives (LiOAr ')(2) and (NaOAr*)(2)'. European Journal of Inorganic Chemistry, (18):3495-3500. [Details] |
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| Burford, N.,Phillips, A. D.,Spinney, H. A.,Robertson, K. N.,Cameron, T. S.; (2003) 'Chalcogeno-urea ligands on a phosphadiazonium Lewis acceptor: A new synthetic approach to Ch-P bonds (Ch = O, S, Se)'. Inorganic Chemistry, 42 (16):4949-4954. [Details] |
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| Burford, N.,Losier, P.,Phillips, A. D.,Ragogna, P. J.,Cameron, T. S.; (2003) 'Nitrogen ligands on phosphorus(III) Lewis acceptors: A versatile new synthetic approach to unusual N-P structural arrangements'. Inorganic Chemistry, 42 (4):1087-1091. [Details] |
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| Hardman, N. J.,Wright, R. J.,Phillips, A. D.,Power, P. P.; (2003) 'Structures, bonding, and reaction chemistry of the neutral organogallium(I) compounds (GaAr)(n) (n=1 or 2) (Ar = terphenyl or related ligand): An experimental investigation of Ga-Ga multiple bonding'. Journal of the American Chemical Society, 125 (9):2667-2679. [Details] |
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| Wright, R. J.,Phillips, A. D.,Power, P. P.; (2003) 'The [2+4] Diels-Alder cycloadditon product of a probable dialuminene, Ar ' AlAlAr ' (Ar ' = C6H3-2,6-Dipp(2); Dipp = C6H3-2,6-Pr-2(i)), with toluene'. Journal of the American Chemical Society, 125 (36):10784-10785. [Details] |
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| Richards, A. F.,Phillips, A. D.,Olmstead, M. M.,Power, P. P.; (2003) 'Isomeric forms of divalent heavier group 14 element hydrides: Characterization of Ar '(H)GeGe(H)Ar ' and Ar '(H)(2)GeGeAr 'center dot PMe3 (Ar ' = C6H3-2,6-Dipp(2); Dipp = C6H3-2,6-Pr-2(i))'. Journal of the American Chemical Society, 125 (11):3204-3205. [Details] |
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| Wright, R. J.,Phillips, A. D.,Allen, T. L.,Fink, W. H.,Power, P. P.; (2003) 'Synthesis and characterization of the monomeric imides Ar ' MNAr '' (M = Ga or In; Ar ' or Ar '' = terphenyl ligands) with two-coordinate gallium and indium'. Journal of the American Chemical Society, 125 (7):1694-1695. [Details] |
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| Pu, L. H.,Phillips, A. D.,Richards, A. F.,Stender, M.,Simons, R. S.,Olmstead, M. M.,Power, P. P.; (2003) 'Germanium and tin analogues of alkynes and their reduction products'. Journal of the American Chemical Society, 125 (38):11626-11636. [Details] |
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| Eichler, B. E.,Phillips, A. D.,Haubrich, S. T.,Mork, B. V.,Power, P. P.; (2002) 'Synthesis, structures, and spectroscopy of the metallostannylenes (eta(5)-C5H5)(CO)(3)M-Sn-C6H3-2,6-Ar-2 (M = Cr, Mo, W; Ar=C6H2-2,4,6-Me-3, C6H2-2,4,6-Pr-3(i))'. Organometallics, 21 (25):5622-5627. [Details] |
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| Stender, M.,Phillips, A. D.,Power, P. P.; (2002) 'Formation of [Ar*Ge{CH2C(Me)C(Me)CH2}CH2C(Me)=](2) (Ar* = C6H3-2,6-Trip(2); Trip = C6H2-2,4,6-i-Pr-3) via reaction of Ar*GeGeAr* with 2,3-dimethyl-1,3-butadiene: evidence for the existence of a germanium analogue of an alkyne'. Chemical Communications, (12):1312-1313. [Details] |
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| Burford, N.,Cameron, T. S.,Conroy, K. D.,Ellis, B.,Macdonald, C. L. B.,Ovans, R.,Phillips, A. D.,Ragogna, P. J.,Walsh, D.; (2002) 'Sequential dehydrochloride coupling of trichlorophosphine with 2,6-di-isopropylaniline: aminophosphine precursors to phosphetidines'. Canadian Journal of Chemistry-Revue Canadienne De Chimie, 80 (11):1404-1409. [Details] |
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| Stender, M.,Phillips, A. D.,Wright, R. J.,Power, P. P.; (2002) 'Synthesis and characterization of a digermanium analogue of an alkyne'. Angewandte Chemie-International Edition, 41 (10):1785-+. [Details] |
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| Hardman, N. J.,Wright, R. L.,Phillips, A. D.,Power, P. P.; (2002) 'Synthesis and characterization of the neutral "digallene" Ar ' GaGaAr ' and its reduction to Na2Ar ' GaGaAr ' (Ar '=2,6-Dipp(2)C(6)H(3), Dipp 2,6-iPr(2)C(6)H(3))'. Angewandte Chemie-International Edition, 41 (15):2842-+. [Details] |
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| Hardman, N. J.,Phillips, A. D.,Power, P. P.; (2002) 'Bonding and reactivity of a beta-diketiminate, gallium(I), carbene analogue'. Group 13 Chemistry: From Fundamentals to Applications, 822 :2-15. [Details] |
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| Phillips, A. D.,Power, P. P.; (2002) 'Models for bonding in the alkali metal-gallium clusters K2Ga4(C6H3-2,6-Trip(2))(2) and Na(2)Ga(4)Trip(6) (Trip = C6H2-2,4,6-i-Pr-3): Importance of alkali metal-aryl interactions'. Journal of Cluster Science, 13 (4):569-586. [Details] |
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| Phillips, A. D.,Wright, R. J.,Olmstead, M. M.,Power, P. P.; (2002) 'Synthesis and characterization of 2,6-Dipp(2)-H3C6SnSnC6H3-2,6-Dipp(2) (Dipp = C6H3-2,6-Pr(i)2): A tin analogue of an alkyne'. Journal of the American Chemical Society, 124 (21):5930-5931. [Details] |
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| Wright, R. J.,Phillips, A. D.,Hardman, N. J.,Power, P. P.; (2002) 'The "diindene" ArInInAr (Ar = C6H3-2,6-dipp(2), dipp = C6H3-2,6-Pr-2(i)). Dimeric versus monomeric in(I) aryls: para-substituent effects in terphenyl ligands'. Journal of the American Chemical Society, 124 (29). [Details] |
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| Burford, N.,Cameron, T. S.,Conroy, K. D.,Ellis, B.,Lumsden, M.,Macdonald, C. L. B.,McDonald, R.,Phillips, A. D.,Ragogna, P. J.,Schurko, R. W.,Walsh, D.,Wasylishen, R. E.; (2002) 'Transformations between monomeric, dimeric, and trimeric phosphazanes: Oligomerizing NP analogues of olefins'. Journal of the American Chemical Society, 124 (47):14012-14013. [Details] |
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| Stender, M.,Phillips, A. D.,Power, P. P.; (2001) 'Characterization and bonding of the cation [Ge{N(C6H3-2,6-i-Pr-2)CMe}(2)CH](+): Comparison with the isoelectronic Ga{N(C6H3-2,6-i-Pr-2)CMe}(2)CH'. Inorganic Chemistry, 40 (21):5314-5315. [Details] |
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| Burford, N.,Cameron, T. S.,Lam, K. C.,LeBlanc, D. J.,Macdonald, C. L. B.,Phillips, A. D.,Rheingold, A. L.,Stark, L.,Walsh, D.; (2001) 'Synthesis and characterization of an homologous series of bis(amido)diazadipnictetidines (Pnict = P, As, Sb, Bi)'. Canadian Journal of Chemistry-Revue Canadienne De Chimie, 79 (3):342-348. [Details] |
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| Bernard, G. M.,Wasylishen, R. E.,Phillips, A. D.; (2000) 'A carbon-13 and deuterium NMR investigation of solid platinum-ethylene complexes: Zeise's salt and Pt(eta(2)-C2H4)(PPh3)(2)'. Journal of Physical Chemistry A, 104 (34):8131-8141. [Details] |
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| Burford, N.,Cameron, T. S.,LeBlanc, D. J.,Phillips, A. D.,Concolino, T. E.,Lam, K. C.,Rheingold, A. L.; (2000) 'Iminophosphide bonding environments from carbene complexes of iminophosphines'. Journal of the American Chemical Society, 122 (22):5413-5414. [Details] |
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| Burford, N.,Cameron, T. S.,Robertson, K. N.,Phillips, A. D.,Jenkins, H. A.; (2000) 'Nitrogen ligands on a phosphinic Lewis acceptor including a 2,2 '-dipyridyl chelate complex'. Chemical Communications, (21):2087-2088. [Details] |
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| Schurko, R. W.,Wasylishen, R. E.,Phillips, A. D.; (1998) 'A definitive example of aluminum-27 chemical shielding anisotropy'. Journal of Magnetic Resonance, 133 (2):388-394. [Details] |
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| Burford, N.,Phillips, A. D.,Schurko, R. W.,Wasylishen, R. E.,Richardson, J. F.; (1997) 'Isolation and comprehensive solid state characterization of Cl3Al-O-PCl3'. Chemical Communications, (24):2363-2364. [Details] |
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Honours and Awards
| Year: 2008. Title: Stokes Lectureship |
| Year: 2006. Title: Marie Curie Intra European Fellowship |
| Year: 1997. Title: Walter C. Sumner Memorial Fellowship |
Associations
| Association: American Chemical Society, Function/Role: Member |
| Association: Swiss Chemical Society, Function/Role: Member |
Languages
| English: |
| Italian: |
Outreach Activities
| Primary School Demonstrations (ACCESS) |
Internal Collaborators
| Dr. C. Murphy: Microbiology; UCD.
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External Collaborators
| Dr. C. Hartinger: Department of Inorganic Chemistry; University of Vienna, Vienna, Austria. Prof. P. J. Dyson: ISIC, EPFL, Vaud, Switzerland. |
Teaching Interests
| Inorganic, Biological Inorganic, Organometallic, Main group chemistry. |
Recent Postgraduates
Current Postgraduate Students
| Dominique Schreiber, Doctor of Philosophy (PhD) - Thesis Supervisor |