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Researchers at UCD

Dermot Brougham

Senior Lecturer

School Of Chemistry
Science Centre - South
Belfield
Dublin 4

Tel: +353 1 7162077
Email: dermot.brougham@ucd.ie

Biography

Dermot Brougham his B.Sc. and Ph.D. degrees from UCD,th elatter in computational organometallic chemistry working under the supervisionof Prof David Brown and Dr Noel Fitzpatrick. He subsequently undertook postdoctoral
work at Queen Mary University of London and the University of Nottingham, working in NMR spectroscopy and relaxometry. His first academic position was in the School of Chemical Sciences, DCU and he moved to the Schol of Chemistry, UCD, in 2016. His research is in the use of NMR to study dynamic processes in condensed matter, and the
application of these measurements in developing nano-structured materials for bioapplications.
 

Publications

     

Peer Reviewed Journals

Aime, S., Barrie, P.J., Brougham, D.F., Gobetto, R., Hawkes, G.E. (1995) '1H MAS NMR spectra of transition metal carbonyl hydrides'. Inorganic Chemistry, 34 (13):3557-3559. Available Online [Details]
Brougham, D.F., Horsewill, A.J., Ikram, A., Ibberson, R.M., McDonald, P.J., Pinter-Krainer, M. (1996) 'The correlation between hydrogen bond tunneling dynamics and the structure of benzoic acid dimers'. Journal of Chemical Physics, 105 (3):979-982. Available Online [Details]
Brougham, D.F., Barrie, P.J., Hawkes, G.E., Abrahams, I., Motevalli, M., Brown, D.A., Long, G.J. (1996) 'Solid State Dynamics of Tricarbonyl(η-1,5-cyclohexadienylium)iron Tetrafluoroborate and Tricarbonyl(η-1,5-cycloheptadienylium)iron Tetrafluoroborate'. Inorganic Chemistry, 35 (19):5595-5602. Available Online [Details]
Brougham, D.F., Horsewill, A.J., Jenkinson, R.I. (1997) 'Proton transfer dynamics in the hydrogen bond: A direct measurement of the incoherent tunnelling rate by NMR and the quantum-to-classical transition'. Chemical Physics Letters, 272 (1-2):69-74. Available Online [Details]
Neumann, M., Brougham, D.F., McGloin, C.J., Johnson, M.R., Horsewill, A.J., Trommsdorff, H.P. (1998) 'Proton tunneling in benzoic acid crystals at intermediate temperatures: Nuclear magnetic resonance and neutron scattering studies'. Journal of Chemical Physics, 109 (17):7300-7311. Available Online [DOI] [Details]
Horsewill, A.J., Brougham, D.F., Jenkinson, R.I., McGloin, C.J., Trommsdorff, H.P., Johnson, M.R. (1998) 'The quantum dynamics of proton transfer in the hydrogen bond'. Berichte der Bunsengesellschaft/Physical Chemistry Chemical Physics, 102 (3):317-324. Available Online [Details]
Brougham, D.F., Caciuffo, R., Horsewill, A.J. (1999) 'Coordinated proton tunnelling in a cyclic network of four hydrogen bonds in the solid state'. Nature, 397 (6716):241-243. Available Online [DOI] [Details]
Brougham, D.F., Horsewill, A.J., Trommsdorff, H.P. (1999) 'A field-cycling NMR relaxometry investigation of proton tunnelling in a partially disordered system of hydrogen bonds'. Chemical Physics, 243 (1-2):189-199. Available Online [Details]
Guan, H., Brougham, D., Sorbie, K.S., Packer, K.J. (2002) 'Wettability effects in a sandstone reservoir and outcrop cores from NMR relaxation time distributions'. Journal of Petroleum Science and Engineering, 34 (1-4):35-54. Available Online [DOI] [Details]
Byrne, S.J., Corr, S.A., Gun'ko, Y.K., Kelly, J.M., Brougham, D.F., Ghosh, S. (2004) 'Magnetic nanoparticle assemblies on denatured DNA show unusual magnetic relaxivity and potential applications for MRI'. Chemical Communications, 10 (22):2560-2561. Available Online [DOI] [Details]
Gunnlaugsson, T., Brougham, D.F., Fanning, A.-M., Nieuwenhuyzen, M., O'Brien, J.E., Viguier, R. (2004) 'Effect on pKa of metal-bound water molecules in lanthanide ion-induced cyclen cavities'. Organic Letters, 6 (26):4805-4808. Available Online [DOI] [Details]
Murray, E., Brougham, D.F. (2005) 'NMRD of polyaniline-based conducting polymers'. Synthetic Metals, 155 (3):681-683. Available Online [DOI] [Details]
Corr, S.A., O'Byrne, A., Gun'ko, Y.K., Ghosh, S., Brougham, D.F., Mitchell, S., Volkov, Y., Prina-Mello, A. (2006) 'Magnetic-fluorescent nanocomposites for biomedical multitasking'. Chemical Communications, (43):4474-4476. Available Online [DOI] [Details]
Krasnikov, S.A., Hanson, C.J., Brougham, D.F., Cafolla, A.A. (2007) 'Dimer ordering of CuTtertBuPc molecules on the Ag/Si(111)-( 3 ÿ 3) R30° surface: A scanning tunnelling microscopy/spectroscopy study'. Journal of Physics Condensed Matter, 19 (44). Available Online [DOI] [Details]
Corr, S.A., Byrne, S.J., Tekoriute, R., Meledandri, C.J., Brougham, D.F., Lynch, M., Kerskens, C., O'Dwyer, L., Gun'ko, Y.K. (2008) 'Linear assemblies of magnetic nanoparticles as MRI contrast agents'. Journal of the American Chemical Society, 130 (13):4214-4215. Available Online [DOI] [Details]
Murray, E., Brougham, D.F., Stankovic, J., Abrahams, I. (2008) 'Conductivity and fluoride ion dynamics in α-PbSnF4; 19F field-cycling NMR and diffraction studies'. Journal of Physical Chemistry C, 112 (14):5672-5678. Available Online [DOI] [Details]
Corr, S.A., Gun'ko, Y.K., Tekoriute, R., Meledandri, C.J., Brougham, D.F. (2008) 'Poly(sodium-4-styrene)sulfonate-iron oxide nanocomposite dispersions with controlled magnetic resonance properties'. Journal of Physical Chemistry C, 112 (35):13324-13327. Available Online [DOI] [Details]
Gottschalk, M., Ivanova, G., Collins, D.M., Eustace, A., O'Connor, R., Brougham, D.F. (2008) 'Metabolomic studies of human lung carcinoma cell lines using in vitro 1H NMR of whole cells and cellular extracts'. NMR in Biomedicine, 21 (8):809-819. Available Online [DOI] [Details]
Murray, E., Carty, D., Innis, P.C., Wallace, G.G., Brougham, D.F. (2008) 'Field-cycling NMR relaxometry study of dynamic processes in conducting polyaniline'. Journal of Physical Chemistry C, 112 (45):17688-17693. Available Online [DOI] [Details]
Ivanova, G.I., Cabrita, E.J., O'Connor, R., Eustace, A.J., Brougham, D.F. (2008) 'Application of diffusion-ordered spectroscopy for the analysis of cancer related biological samples'. Bulgarian Chemical Communications, 40 (4):464-468. Available Online [Details]
Meledandri, C.J., Stolarczyk, J.K., Ghosh, S., Brougham, D.F. (2008) 'Nonaqueous magnetic nanoparticle suspensions with controlled particle size and nuclear magnetic resonance properties'. Langmuir, 24 (24):14159-14165. Available Online [DOI] [Details]
Stolarczyk, J.K., Ghosh, S., Brougham, D.F. (2009) 'Controlled growth of nanoparticle clusters through competitive stabilizer desorption'. Angewandte Chemie - International Edition, 48 (1):175-178. Available Online [DOI] [Details]
Simeonova, M., Ivanova, G., Enchev, V., Markova, N., Kamburov, M., Petkov, C., Devery, A., O'Connor, R., Brougham, D. (2009) 'Physicochemical characterization and in vitro behavior of daunorubicin-loaded poly(butylcyanoacrylate) nanoparticles'. Acta Biomaterialia, 5 (6):2109-2121. Available Online [DOI] [Details]
Meledandri, C.J., Perlo, J., Farrher, E., Brougham, D.F., Anoardo, E. (2009) 'Interpretation of molecular dynamics on different time scales in unilamellar vesicles using field-cycling NMR relaxometry'. Journal of Physical Chemistry B, 113 (47):15532-15540. Available Online [DOI] [Details]
Ghosh, S., Carty, D., Clarke, S.P., Corr, S.A., Tekoriute, R., Gun'Ko, Y.K., Brougham, D.F. (2010) 'NMR studies into colloidal stability and magnetic order in fatty acid stabilised aqueous magnetic fluids'. Physical Chemistry Chemical Physics, 12 (42):14009-14016. Available Online [DOI] [Details]
Brougham, D.F., Ivanova, G., Gottschalk, M., Collins, D.M., Eustace, A.J., O'Connor, R., Havel, J. (2011) 'Artificial neural networks for classification in metabolomic studies of whole cells using 1H Nuclear Magnetic Resonance'. Journal of Biomedicine and Biotechnology, 2011 . Available Online [DOI] [Details]
Meledandri, C.J., Ninjbadgar, T., Brougham, D.F. (2011) 'Size-controlled magnetoliposomes with tunable magnetic resonance relaxation enhancements'. Journal of Materials Chemistry, 21 (1):214-222. Available Online [DOI] [Details]
Davies, G.-L., Corr, S.A., Meledandri, C.J., Briode, L., Brougham, D.F., Gun'Ko, Y.K. (2011) 'NMR relaxation of water in nanostructures: Analysis of ferromagnetic cobalt-ferrite polyelectrolyte nanocomposites'. ChemPhysChem, 12 (4):772-776. Available Online [DOI] [Details]
Meledandri, C.J., Stolarczyk, J.K., Brougham, D.F. (2011) 'Hierarchical gold-decorated magnetic nanoparticle clusters with controlled size'. ACS Nano, 5 (3):1747-1755. Available Online [DOI] [Details]
Perlo, J., Meledandri, C.J., Anoardo, E., Brougham, D.F. (2011) 'Temperature and size-dependence of membrane molecular dynamics in unilamellar vesicles by fast field-cycling NMR relaxometry'. Journal of Physical Chemistry B, 115 (13):3444-3451. Available Online [DOI] [Details]
Davis, C., Carberry, S., Schrettl, M., Singh, I., Stephens, J.C., Barry, S.M., Kavanagh, K., Challis, G.L., Brougham, D., Doyle, S. (2011) 'The role of glutathione S-transferase GliG in gliotoxin biosynthesis in Aspergillus fumigatus'. Chemistry and Biology, 18 (4):542-552. Available Online [DOI] [Details]
Xiao, L., Li, J., Brougham, D.F., Fox, E.K., Feliu, N., Bushmelev, A., Schmidt, A., Mertens, N., Kiessling, F., Valldor, M., Fadeel, B., Mathur, S. (2011) 'Water-soluble superparamagnetic magnetite nanoparticles with biocompatible coating for enhanced magnetic resonance imaging'. ACS Nano, 5 (8):6315-6324. Available Online [DOI] [Details]
Sadeghifar, H., Filpponen, I., Clarke, S.P., Brougham, D.F., Argyropoulos, D.S. (2011) 'Production of cellulose nanocrystals using hydrobromic acid and click reactions on their surface'. Journal of Materials Science, 46 (22):7344-7355. Available Online [DOI] [Details]
Ninjbadgar, T., Brougham, D.F. (2011) 'Epoxy ring opening phase transfer as a general route to water dispersible superparamagnetic Fe 3O 4 nanoparticles and their application as positive MRI contrast agents'. Advanced Functional Materials, 21 (24):4769-4775. Available Online [DOI] [Details]
Meledandri, C.J., Brougham, D.F. (2012) 'Low field magnetic resonance techniques in the development of nanomaterials for biomedical applications'. Analytical Methods, 4 (2):331-341. Available Online [DOI] [Details]
Das, S.K., Dickinson, C., Lafir, F., Brougham, D.F., Marsili, E. (2012) 'Synthesis, characterization and catalytic activity of gold nanoparticles biosynthesized with Rhizopus oryzae protein extract'. Green Chemistry, 14 (5):1322-1334. Available Online [DOI] [Details]
Sheridan, J.G., Heidelberg, A., Brougham, D.F., Nellist, P.D., Langford, R.M., Boland, J.J. (2012) 'Self-assembly of LiMo 3Se 3 nanowire networks from nanoscale building-blocks in solution'. Langmuir, 28 (43):15344-15349. Available Online [DOI] [Details]
Lartigue, L., Hugounenq, P., Alloyeau, D., Clarke, S.P., Lévy, M., Bacri, J.-C., Bazzi, R., Brougham, D.F., Wilhelm, C., Gazeau, F. (2012) 'Cooperative organization in iron oxide multi-core nanoparticles potentiates their efficiency as heating mediators and MRI contrast agents'. ACS Nano, 6 (12):10935-10949. Available Online [DOI] [Details]
Khan, A.A., Fox, E.K., Górzny, M.L., Nikulina, E., Brougham, D.F., Wege, C., Bittner, A.M. (2013) 'PH control of the electrostatic binding of gold and iron oxide nanoparticles to tobacco mosaic virus'. Langmuir, 29 (7):2094-2098. Available Online [DOI] [Details]
Borase, T., Ninjbadgar, T., Kapetanakis, A., Roche, S., O'Connor, R., Kerskens, C., Heise, A., Brougham, D.F. (2013) 'Stable aqueous dispersions of glycopeptide-grafted selectably functionalized magnetic nanoparticles'. Angewandte Chemie - International Edition, 52 (11):3164-3167. Available Online [DOI] [Details]
Kozlowska, D., Biswas, S., Fox, E.K., Wu, B., Bolster, F., Edupuganti, O.P., Torchilin, V., Eustace, S., Botta, M., O'Kennedy, R., Brougham, D.F. (2014) 'Gadolinium-loaded polychelating amphiphilic polymer as an enhanced MRI contrast agent for human multiple myeloma and non Hodgkin's lymphoma (human Burkitt's lymphoma)'. RSC Advances, 4 (35):18007-18016. Available Online [DOI] [Details]
Fraenza, C.C., Meledandri, C.J., Anoardo, E., Brougham, D.F. (2014) 'The effect of cholesterol on membrane dynamics on different timescales in lipid bilayers from fast field-cycling NMR relaxometry studies of unilamellar vesicles'. ChemPhysChem, 15 (3):425-435. Available Online [DOI] [Details]
Al-Hamaoy, A., Chikarakara, E., Jawad, H., Gupta, K., Kumar, D., Rao, M.S.R., Krishnamurthy, S., Morshed, M., Fox, E., Brougham, D., He, X., Vázquez, M., Brabazon, D. (2014) 'Liquid Phase - Pulsed Laser Ablation: A route to fabricate different carbon nanostructures'. Applied Surface Science, 302 :141-144. Available Online [DOI] [Details]
Marangon, I., Ménard-Moyon, C., Kolosnjaj-Tabi, J., Béoutis, M.L., Lartigue, L., Alloyeau, D., Pach, E., Ballesteros, B., Autret, G., Ninjbadgar, T., Brougham, D.F., Bianco, A., Gazeau, F. (2014) 'Covalent functionalization of multi-walled carbon nanotubes with a gadolinium chelate for efficient T1-weighted magnetic resonance imaging'. Advanced Functional Materials, 24 (45):7173-7186. Available Online [DOI] [Details]
Bagga, K., Brougham, D.F., Keyes, T.E., Brabazon, D. (2015) 'Magnetic and noble metal nanocomposites for separation and optical detection of biological species'. Physical Chemistry Chemical Physics, 17 (42):27968-27980. Available Online [DOI] [Details]
Alwy, A., Clarke, S.P., Brougham, D.F., Twamley, B., Paull, B., White, B., Connolly, D. (2015) 'Development of a silica monolith modified with Fe3O4 nano-Particles in centrifugal spin column format for the extraction of phosphorylated compounds'. Journal of Separation Science, 38 (2):283-290. Available Online [DOI] [Details]
Ninjbadgar, T., Fox, E.K., Hierrezuelo, J., El Haddassi, F., Brougham, D.F. (2015) 'Monodisperse magnetic nanoparticle assemblies prepared at scale by competitive stabiliser desorption'. Journal of Materials Chemistry B, 3 (44):8638-8643. Available Online [DOI] [Details]
Sreeremya, T.S., Krishnan, A., Remani, K.C., Patil, K.R., Brougham, D.F., Ghosh, S. (2015) 'Shape-selective oriented cerium oxide nanocrystals permit assessment of the effect of the exposed facets on catalytic activity and oxygen storage capacity'. ACS applied materials & interfaces, 7 (16):8545-8555. Available Online [DOI] [Details]