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Researchers at UCD

researcher

Earle Waghorne

Pensioners-Salaries

CSCB Building
Belfield
Dublin 4

Tel: +353 1 7162132
Email: earle.waghorne@ucd.ie

Biography

B.Sc. University of Guelph (1969), Ph.D. from the Australian National University (1973) (supervisor James Parker). Department of Education Post-doctoral fellow at UCD (1973 - 5) Joined UCD in 1975. Currently deputy head of School.
Fellow, Internaitonal Union of Pure and Applied Chemistry, Member of the IUPAC Subcommittee on Solubility and Equilibrium Data, Fellow, Institute of Chemistry of Ireland, ICI representative to the Ownership Board of Physical Chemistry Chemical Physics, Member of the editorial board, Journal of Solution Chemistry.

Publications

 

Book Chapters

Waghorne, W.E.; (2006) 'Chapter 2 Thermodynamics of Electrolyte Solubility' In: Developments and Applications in Solubility. Cambridge: Royal Society of Chemistry. [Details]
 

Peer Reviewed Journals

Feakins, D., Bates, F. M., Waghorne, W. E., ; (2008) 'Quasi-thermodynamics of viscous flow of electrolyte solutions in aqueous, non-aqueous and mixed aqueous solvents'. Journal of Solution Chemistry, 37 (6):727-747. [Details]
Behbehani, GR, Ghammamy, S, Waghorne, WE, ; (2006) 'Enthalpies of transfer of acetonitrile from water to aqueous methanol, ethanol and dimethylsulphoxide mixtures at 298.15 K'. Thermochimica Acta, 448 (1):37-40. [Details]
Bebahani, GR, Dunnion, D, Falvey, P, Hickey, K, Meade, M, McCarthy, Y, Symons, MCR, Waghorne, WE, ; (2000) 'Nonelectrolyte solvation in aqueous dimethyl sulfoxide - A calorimetric and infrared spectroscopic study'. Journal of Solution Chemistry, 29 (6):521-539. [Details]
FEAKINS, D, MULLALLY, J, WAGHORNE, WE, ; (1993) 'ENTHALPIES OF TRANSFER OF SODIUM AND POTASSIUM-CHLORIDES FROM WATER TO AQUEOUS 1,4-DIOXANE MIXTURES AT 25-DEGREES-C'. Journal of Solution Chemistry, 22 (4):311-319. [Details]
FEAKINS, D, BATES, FM, WAGHORNE, WE, LAWRENCE, KG, ; (1993) 'RELATIVE VISCOSITIES AND QUASI-THERMODYNAMICS OF SOLUTIONS OF TERT-BUTYL ALCOHOL IN THE METHANOL-WATER SYSTEM - A DIFFERENT VIEW OF THE ALKYL WATER INTERACTION'. Journal of the Chemical Society-Faraday Transactions, 89 (18):3381-3388. [Details]
EATON, G, SYMONS, MCR, RASTOGI, PP, ODUINN, C, WAGHORNE, WE, ; (1992) 'SOLVATION OF SOME AMIDES IN MIXED-SOLVENT SYSTEMS - COMPARISON OF THE RESULTS OF INFRARED SPECTROSCOPIC AND CALORIMETRIC MEASUREMENTS'. Journal of the Chemical Society-Faraday Transactions, 88 (8):1137-1142. [Details]
FEAKINS, D, HOGAN, P, ODUINN, C, WAGHORNE, WE, ; (1992) 'ENTHALPIES OF TRANSFER OF FORMAMIDE, N-METHYLFORMAMIDE AND N,N-DIMETHYLFORMAMIDE FROM WATER TO AQUEOUS ACETONITRILE MIXTURES AT 298-K'. Journal of the Chemical Society-Faraday Transactions, 88 (3):423-425. [Details]
EATON, G, SYMONS, MCR, RASTOGI, PP, ODUINN, C, WAGHORNE, WE, ; (1992) 'SOLVATION OF SOME AMIDES IN MIXED-SOLVENT SYSTEMS - COMPARISON OF THE RESULTS OF INFRARED SPECTROSCOPIC AND CALORIMETRIC MEASUREMENTS'. Journal of the Chemical Society-Faraday Transactions, 88 (8):1137-1142. [Details]
CARTHY, G, FEAKINS, D, ODUINN, C, WAGHORNE, WE, ; (1991) 'ENTHALPIES OF TRANSFER OF FORMAMIDE, N-METHYLFORMAMIDE, N,N-DIMETHYLFORMAMIDE AND UREA FROM WATER TO SOME AQUEOUS ALCOHOL SOLVENT SYSTEMS AT 298-K'. Journal of the Chemical Society-Faraday Transactions, 87 (15):2447-2452. [Details]
COSTIGAN, A, FEAKINS, D, MCSTRAVICK, I, ODUINN, C, RYAN, J, WAGHORNE, WE, ; (1991) 'ENTHALPIES OF TRANSFER OF SOME NONELECTROLYTES FROM ACETONITRILE TO ACETONITRILE METHANOL MIXTURES'. Journal of the Chemical Society-Faraday Transactions, 87 (15):2443-2446. [Details]
FEAKINS, D, MULLALLY, J, WAGHORNE, WE, ; (1991) 'ENTHALPIES OF TRANSFER OF TETRABUTYLAMMONIUM BROMIDE AS INDICATORS OF THE STRUCTURE OF AQUEOUS SOLVENTS - AQUEOUS METHANOL, ETHANOL, PROPAN-1-OL, 2-METHYLPROPAN-2-OL AND 1,4-DIOXANE SYSTEMS'. Journal of the Chemical Society-Faraday Transactions, 87 (1):87-91. [Details]
ONEILL, RD, SHEIHA, L, WAGHORNE, WE, FEAKINS, D, ; (1990) 'A NEW METHOD FOR DETERMINING IONIC SOLVENT TRANSPORT NUMBERS AND FREE-ENERGY OF TRANSFER OF ELECTROLYTES FROM WATER TO MIXED AQUEOUS SOLVENTS'. Journal of the Chemical Society-Chemical Communications, -1 (2):99-100. [Details]
FEAKINS, D, MULLALLY, J, WAGHORNE, WE, ; (1990) 'ENTHALPIES OF TRANSFER OF 2-METHYL-2-PROPANOL FROM WATER TO MIXTURES OF WATER WITH METHANOL, ETHANOL AND 1,4-DIOXANE'. Journal of Solution Chemistry, 19 (4):401-408. [Details]
FEAKINS, D, CANNING, FM, MULLALLY, JJ, WAGHORNE, WE, ; (1989) 'THE THERMODYNAMICS OF SOLUTIONS'. Pure and Applied Chemistry, 61 (2):133-142. [Details]
FEAKINS, D, JOHNSON, KF, WAGHORNE, WE, ; (1989) 'THERMODYNAMICS OF ION SOLVATION IN MIXED AQUEOUS SOLVENTS .3. EFFECT OF STERIC HINDRANCE ON THE FREE-ENERGIES OF TRANSFER OF CATIONS TO 5-PERCENT AND 20-PERCENT (W/W) PROPAN-1-OL-WATER MIXTURES'. Proceedings of The Royal Irish Academy Section B-Biological Geological and Chemical Science, 89 (6-52):321-327. [Details]
WAGHORNE, WE, FALLON, BA, ; (1989) 'FREE-ENERGIES OF TRANSFER OF SILVER BROMIDE FROM METHANOL TO METHANOL-DIMETHYLSULFOXIDE MIXTURES AT 298K'. Proceedings of The Royal Irish Academy Section B-Biological Geological and Chemical Science, 89 (6-52):369-374. [Details]
PILLAI, KC, WAGHORNE, WE, WILSON, O, ; (1988) 'AN ELECTROCHEMICAL STUDY OF THE MERCURY LITHIUM PERCHLORATE INTERFACE IN DIMETHYLSULFOXIDE+PROPYLENE CARBONATE MIXTURES AT 298-K'. Journal of Electroanalytical Chemistry, 252 (1):151-168. [Details]
FEAKINS, D, HICKEY, BE, KNOX, M, MCCARTHY, PJ, WAGHORNE, WE, ; (1987) 'CORRELATIONS BETWEEN THE TRANSFER THERMODYNAMICS OF SIMPLE ELECTROLYTES AND STRUCTURAL PARAMETERS WITH PARTICULAR REFERENCE TO STERIC HINDRANCE'. Journal of the Chemical Society-Chemical Communications, -1 (8):611-613. [Details]
FEAKINS, D, ODUINN, CC, WAGHORNE, WE, ; (1987) 'ENTHALPIES OF TRANSFER OF N-METHYLFORMAMIDE, FORMAMIDE, AND N,N-DIMETHYLFORMAMIDE FROM METHANOL TO METHANOL + DIMETHYLSULFOXIDE MIXTURES'. Journal of Solution Chemistry, 16 (11):907-915. [Details]
BROWN, DA, GLASS, WK, TOMA, HJ, WAGHORNE, WE, ; (1987) 'DITHIOCARBAMATES OF TUNGSTEN(III) AND TUNGSTEN(IV)'. Journal of the Chemical Society-Dalton Transactions, -1 (11):2531-2536. [Details]
CARTHY, G, FEAKINS, D, WAGHORNE, WE, ; (1987) 'ENTHALPIES OF TRANSFER OF TETRA-ALKYLAMMONIUM HALIDES FROM WATER TO WATER PROPAN-1-OL MIXTURES AT 25-DEGREES-C'. Journal of The Chemical Society-Faraday Transactions I, 83 (NA):2585-2592. [Details]
CRUDDEN, J, DELANEY, GM, FEAKINS, D, OREILLY, PJ, WAGHORNE, WE, LAWRENCE, KG, ; (1986) 'THE VISCOSITY AND STRUCTURE OF SOLUTIONS .3. INTERPRETATION OF THE THERMODYNAMIC ACTIVATION PARAMETERS FOR PROPAN-1-OL WATER-ELECTROLYTE SYSTEMS'. Journal of The Chemical Society-Faraday Transactions I, 82 (NA):2207-2219. [Details]
FEAKINS, D, WAGHORNE, WE, LAWRENCE, KG, ; (1986) 'THE VISCOSITY AND STRUCTURE OF SOLUTIONS .1. A NEW THEORY OF THE JONES-DOLE B-COEFFICIENT AND THE RELATED ACTIVATION PARAMETERS - APPLICATION TO AQUEOUS-SOLUTIONS'. Journal of The Chemical Society-Faraday Transactions I, 82 (NA):563-568. [Details]
CRUDDEN, J, DELANEY, GM, FEAKINS, D, OREILLY, PJ, WAGHORNE, WE, LAWRENCE, KG, ; (1986) 'THE VISCOSITY AND STRUCTURE OF SOLUTIONS .2. MEASUREMENT OF THE B-COEFFICIENT OF VISCOSITY FOR ALKALI-METAL CHLORIDES IN PROPAN-1-OL WATER MIXTURES AT 25-DEGREES-C AND 35-DEGREES-C'. Journal of The Chemical Society-Faraday Transactions I, 82 (NA):2195-2206. [Details]
CRONNOLLY, C, PILLAI, KC, WAGHORNE, WE, ; (1986) 'ELECTRODE KINETIC-STUDIES OF THE ZN-2+/ZN(HG) AND LI+/LI(HG) COUPLES IN DIMETHYLSULFOXIDE + PROPYLENE CARBONATE SOLVENT SYSTEMS'. Journal of Electroanalytical Chemistry, 207 (1-2):177-187. [Details]
DEVALERA, E, FEAKINS, D, WAGHORNE, WE, ; (1985) 'RELATIONSHIP BETWEEN THE ENTROPY OF TRANSFER OF A SOLUTE AND THE THERMODYNAMIC FUNCTIONS OF MIXED-SOLVENTS'. Journal of The Chemical Society-Faraday Transactions I, 81 (NA):2703-2710. [Details]
COX, BG, WAGHORNE, WE, ; (1984) 'FREE-ENERGIES, ENTHALPIES AND ENTROPIES OF TRANSFER OF ELECTROLYTES FROM PROPYLENE CARBONATE TO DIMETHYLSULFOXIDE+PROPYLENE CARBONATE MIXTURES AND FROM METHANOL TO ACETONITRILE+METHANOL MIXTURES AT 25-DEGREES-C - FURTHER DEVELOPMENT OF SOLVATION THEORY'. Journal of The Chemical Society-Faraday Transactions I, 80 (NA):1267-1278. [Details]
CARTHY, G, FEAKINS, D, WAGHORNE, WE, ; (1984) 'ENTHALPIES OF TRANSFER AND HYDROPHOBIC HYDRATION - TETRABUTYLAMMONIUM BROMIDE IN THE PROPAN-1-OL + WATER-SYSTEM'. Journal of the Chemical Society-Chemical Communications, -1 (9):588-589. [Details]
FEAKINS, D, ONEILL, RD, WAGHORNE, WE, ; (1983) 'WASHBURN NUMBERS .5. RELATIVE SOLVENT TRANSPORT NUMBERS FOR ION CONSTITUENTS IN THE DIOXAN + WATER AND DIMETHYLSULFOXIDE + WATER-SYSTEMS'. Journal of The Chemical Society-Faraday Transactions I, 79 (NA):2289-2298. [Details]
DEVALERA, E, FEAKINS, D, WAGHORNE, WE, ; (1983) 'RELATIONSHIP BETWEEN THE ENTHALPY OF TRANSFER OF A SOLUTE AND THE THERMODYNAMIC MIXING FUNCTIONS OF MIXED-SOLVENTS'. Journal of The Chemical Society-Faraday Transactions I, 79 (NA):1061-1071. [Details]
FEAKINS, D, ONEILL, RD, WAGHORNE, WE, WARD, AJI, ; (1982) 'WASHBURN NUMBERS .4. THE ERDEY-GRUZ EXPERIMENT - RELATIVE SOLVENT TRANSPORT NUMBERS FOR ION CONSTITUENTS IN MIXTURES OF WATER WITH RAFFINOSE, GLYCINE, ALLYL ALCOHOL, DIMETHYLSULFOXIDE AND DIOXAN'. Journal of The Chemical Society-Faraday Transactions I, 78 (NA):1431-1449. [Details]
WAGHORNE, WE, RUBALCAVA, H, ; (1982) 'INFRARED SPECTROSCOPIC STUDY OF THE EFFECTS OF DIFFERENT CATIONS IN NN-DIMETHYLACETAMIDE AND FULLY DEUTERATED NN-DIMETHYLFORMAMIDE'. Journal of The Chemical Society-Faraday Transactions I, 78 (NA):1199-1207. [Details]
PILLAI, KC, WAGHORNE, WE, ; (1981) 'ELECTRICAL DOUBLE-LAYER STUDIES OF THIOUREA IN CONCENTRATED KCL SOLUTIONS'. Journal of Electroanalytical Chemistry, 125 (2):487-489. [Details]
COX, BG, WAGHORNE, WE, ; (1980) 'THERMODYNAMICS OF ION-SOLVENT INTERACTIONS'. Chemical Society Reviews, 9 (3):381-411. [Details]
WAGHORNE, WE, WARD, AJI, CLUNE, TG, COX, BG, ; (1980) 'EFFECT OF DIFFERENT CATIONS ON THE N-CO ROTATIONAL BARRIER OF N,N-DIMETHYLACETAMIDE - VARIABLE TEMPERATURE PROTON MAGNETIC-RESONANCE STUDY'. Journal of The Chemical Society-Faraday Transactions I, 76 (NA):1131-1137. [Details]
DEVALERA, E, FEAKINS, D, WAGHORNE, WE, ; (1980) 'STUDIES IN ION SOLVATION IN NON-AQUEOUS SOLVENTS AND THEIR AQUEOUS MIXTURES .20. ENTHALPIES OF TRANSFER OF ALKALI-METAL HALIDES IN THE METHANOL WATER-SYSTEM FROM ENTHALPIES OF DILUTION'. Journal of The Chemical Society-Faraday Transactions I, 76 (NA):560-569. [Details]
FEAKINS, D, ONEILL, R, WAGHORNE, WE, WARD, AJI, ; (1979) 'RELATIVE SOLVENT TRANSPORT OF ION CONSTITUENTS IN AQUEOUS ORGANIC-SOLVENTS'. Journal of the Chemical Society-Chemical Communications, -1 (22):1029-1030. [Details]
COX, BG, NATARAJAN, R, WAGHORNE, WE, ; (1979) 'THERMODYNAMIC PROPERTIES FOR TRANSFER OF ELECTROLYTES FROM WATER TO DIMETHYLSULFOXIDE AND TO DIMETHYLSULFOXIDE WATER MIXTURES'. Journal of The Chemical Society-Faraday Transactions I, 75 (NA):1780-1787. [Details]
COX, BG, NATARAJAN, R, WAGHORNE, WE, ; (1979) 'THERMODYNAMIC PROPERTIES FOR TRANSFER OF ELECTROLYTES FROM WATER TO DIMETHYLSULFOXIDE AND TO DIMETHYLSULFOXIDE WATER MIXTURES'. Journal of The Chemical Society-Faraday Transactions I, 75 (NA):1780-1787. [Details]
COX, BG, NATARAJAN, R, WAGHORNE, WE, ; (1979) 'THERMODYNAMIC PROPERTIES FOR TRANSFER OF ELECTROLYTES FROM WATER TO ACETONITRILE AND TO ACETONITRILE+WATER MIXTURES'. Journal of The Chemical Society-Faraday Transactions I, 75 (NA):86-95. [Details]
COX, BG, WAGHORNE, WE, PIGOTT, CK, ; (1979) 'THERMODYNAMIC PROPERTIES FOR TRANSFER OF CATIONS FROM PROPYLENE CARBONATE TO DIMETHYLSULFOXIDE AND TO PROPYLENE CARBONATE + DIMETHYLSULFOXIDE MIXTURES'. Journal of The Chemical Society-Faraday Transactions I, 75 (NA):227-235. [Details]
Waghorne, W.E. with: Hora J., Mc Carthy R.; (2005) 'Enthalpies of transfer of the CH2 moiety into aqueous acetonitrile mixtures; comparison of values from n-alcohols and tetraalkylammonium ions; effect of temperature variation'. Journal of Chemical Thermodynamics, 37 (1):83-88. [Details]
Hora, J; Mc Carthy, R; Waghorne, WE; ; (2005) 'Enthalpies of transfer of the CH2 moiety into aqueous acetonitrile mixtures; comparison of values from n-alcohols and tetraalkylammonium ions; effect of temperature variation'. Journal of Chemical Thermodynamics, 37 (1):83-88. [Details]
Waghorne, W.E. with: Mandal A, Fitzmaurice D, Koll A, Filarowski A, Quinn S, Mukherjee S; (2004) 'Proton transfer reaction of a new orthohydroxy Schiff base at room temperature and 77 K'. Spectrochemica Acta, 60 (4):805-813. [Details]
Waghorne, W.E. with Noban, S. Donohue, P.; (2003) 'Enthalpies of transfer of the -CH2- moiety into aqueous amide solvent systems; values from n-alcohol solutes'. Journal of Physical Chemistry B, 107 (47):13188-13191. [Details]
Waghorne, W.E.; (2003) 'Solubilities of the silver halides in aqueous mixtures of methanol, acetonitrile, and dimethylsulfoxide'. Monatschefte Fur Chemie, 134 (5):655-667. [Details]
Noban, S; Donohue, P; Waghorne, WE; ; (2003) 'Enthalpies of transfer of the -CH2- moiety into aqueous amide solvent systems; values from n-alcohol solutes'. Journal of Physical Chemistry B, 107 (47):13188-13191. [Details]
Guthrie, JP; O'Ferrall, RAM; O'Donoghue, AC; Waghorne, WE; Zrinski, I; ; (2003) 'Estimation of a pK(a) for protonated dimethoxycarbene'. Journal of Physical Organic Chemistry, 16 (8):582-587. [Details]
McStravick, I; Duffy, E; Waghorne, WE; ; (2003) 'Enthalpies of transfer of -CH2- between water and nonaqueous or mixed aqueous solvents. Comparison of values from n-alcohols and tetraakylammonium halides'. Journal of Molecular Liquids, 103 (NA):121-131. [Details]
Waghorne, W.E. with: E. Duggan ; (2003) 'Long-term Evaluation of Production Protocols for Stirred Yoghurts Produced using two Different Cultures'. Milchwissenschaft - Milk Science International, 58 :52-55. [Details]
Waghorne, W.E. With: I. McStravick and E. Duffy ; (2003) 'Enthalpies of Transfer of -CH2- Between Water and Nonaqueous or Mixed Aqueous Solvents. Comparison of values obtained from n-Alcohols and Tetra-akylammonium Halides'. Journal of Molecular Liquids, 103 :121-131. [Details]
Waghorne, W.E. with:Guthrie, JP, O'Ferrall, RAM, O'Donoghue, AC, Zrinski I; (2003) 'Estimation of a pK(a) for protonated dimethoxycarbene'. Journal of Physical Organic Chemistry, 16 (8):582-587. [Details]
Waghorne, W.E. with: S. Petry, S. Furlan, L. Saulnier, J. Cerning and E. Maguin; (2003) 'Comparison of the thickening properties of four Lactobacillus delbrueckii subsp bulgaricus strains and physicochemical characterization of their exopolysaccharides'. FEBS Letters, 221 :285-291. [Details]
Waghorne, W.E. with: A. Koll, A. Filarowski, D. Fitzmaurice, A. Mondal and S. Mukherjee ; (2002) 'Excited State Proton Transfer Reaction of two new Intramolecularly Hydrogen Bonded Schiff Bases at Room Temperature and at 77K'. Spectrochemica Acta, 58 :197-207. [Details]
Bebahani, GRR; Hogan, P; Waghorne, WE; ; (2002) 'Ostwald concentration coefficients of acetonitrile in aqueous mixed solvents: A new, rapid method for measuring the solubilities of volatile solutes'. Journal of Chemical and Engineering Data, 47 (5):1290-1292. [Details]
Behbehani, GR; Dillin, M; Smyth, J; Waghorne, WE; ; (2002) 'Infrared spectroscopic study of the solvation of tetramethylurea in protic plus aprotic mixed solvents'. Journal of Solution Chemistry, 31 (10):811-822. [Details]
Waghorne, W.E. with: G. Rezaei Behbehani, Marie Dillon and Jennifer Smyth ; (2002) 'An Infrared Spectroscopic Study of the Solvation of Tetramethylurea in Protic + Aprotic Mixed Solvents'. Journal of Solution Chemistry, 31 :811-822. [Details]
Waghorne, W.E. with: A. Mandal, D. Fitzmaurice, A. Koll, A. Filarowski, D, Guha and S. Mukherjee ; (2002) 'Ground and excited state proton transfer reaction of two new o-hydroxy Schiff bases in some protic solvents at room temperature and 77 K'. Journal of Photochemistry and Photobiology A-Chemistry, 153 :67-76. [Details]
Waghorne, W.E. with G.Hefter and Yu. Marcus ; (2002) 'Enthalpies of Transfer of Electrolytes and Ions between Water and Mixed Aqueous Solvents'. Chemical Reviews, 102 :2773-2835. [Details]
Waghorne, W.E. with: Gh.R.R. Bebahani and P. Hogan ; (2002) 'Ostwald Concentration Coefficients of Acetonitrile in Aqueous Mixed Solvents; A New, Rapid, Method for Measuring the Solubilities of Volatile Solutes'. Journal of Chemical and Engineering Data, 47 :1290-1292. [Details]
Waghorne, W.E. with: K. Hickey and A. Sacco ; (2001) 'Comparison of the Activation Free Energies for Viscous Flow and for Diffusion in Dilute Solutions; Derivation of the Expression for the Effect of the Solute on the Activation Free energy of Diffusion of the Solvent; Application to Solutions of N,N-Dimethylformamide in Water, Methanol and Acetonitrile'. Journal of Physical Chemistry, 105 :1093-1096. [Details]
Waghorne, W.E. with: K. Hickey ; (2001) 'Viscosities and Volumes of dilute solutions of Formamide in Water + Acetonitrile and for Formamide and N,N-Dimethylformamide in Methanol + Acetonitrile Mixed Solvents; Viscosity B-Coefficients, Activation Free Energies for Viscous Flow and Partial Molar Volumes'. Journal of Chemical and Engineering Data, 46 :851-1857. [Details]
Hickey, K; Waghorne, WE; Sacco, A; ; (2001) 'Comparison of the activation free energies for viscous flow and for diffusion in dilute solutions, derivation of the expression for the effect of the solute on the activation free energy of diffusion of the solvent, and application to solutions of N,N-dimethylformamide in water, methanol, and acetonitrile'. Journal of Physical Chemistry A, 105 (6):1093-1096. [Details]
McStravick, I; Flynn, K; Lambert, J; Teahan, N; Waghorne, WE; ; (2001) 'Enthalpy of transfer of -CH2- between water and organic solvents or mixed aqueous organic solvent systems'. Journal of Molecular Liquids, 94 (2):145-153. [Details]
Hickey, K; Waghorne, WE; ; (2001) 'Viscosities and volumes of dilute solutions of formamide in water plus acetonitrile and for formamide and N,N-dimethylformamide in methanol plus acetonitrile mixed solvents: Viscosity B-coefficients, activation free energies for viscous flow, and partial molar volumes'. Journal of Chemical and Engineering Data, 46 (4):851-857. [Details]
Waghorne, W.E. with: E. Duggan ; (2001) 'Effect of added Chitosan on the Rheological Properties of Acidified Milk Gels '. Progress in Colloid and Polymer Science, 118 :196-201. [Details]
Waghorne, W.E. with: I. McStravick, K. Flynn, J. Lambert and N. Teahan ; (2001) 'Enthalpy of Transfer of CH2 between Water and Organ Solvents of Mixed Aqueous Organic Solvent Systems'. Journal of Molecular Liquids, 94 :145-153. [Details]
Waghorne, W.E.; (2001) 'Viscosities of Electrolyte Solutions'. Philosophical Transactions of the Royal Society, London, 359 :1529-1543. [Details]
Waghorne, W.E. with: Gh. R. Bebahani, D. Dunnion, P. Falvey, K. Hickey, M. Meade, Yvonne McCarthy and M.C.R. Symons ; (2000) 'Nonelectrolyte Solvation in Aqueous Dimethylsulfoxide A Calorimetric and infrared Spectroscopic Study '. Journal of Solution Chemistry, 29 :521-539. [Details]
Waghorne, W.E. with: E.O. Arikainen, J. Earnshaw and A. Wehling ; (1999) 'A Rheo-optical investigation ointo the Viscoelastic Moduli of Acidified Milk Gels'. Applied Rheology, 9 :246-253. [Details]
Waghorne, W.E. with: G. Will, E. Kudriashov, E. Duggan, D. Fitzmaurice, V. Buckin and S. Mukherjee ; (1999) 'Excited State Complex Formation between 3-Aminophthalhydrazine and DNA: a Fluorescence Quenching Reaction'. Spectrochemica Acta, 55 :2711-2717. [Details]
Waghorne, W.E. with: E. Duggan, G. Will, D. Fitzmaurice and S. Mukherjee ; (1999) 'Effect of Hydrogen Bonding on the Electronic Absorption Spectra of some Nucleic Acid Bases'. Journal of Physics, 73B :671-677. [Details]
Waghorne, W.E. with: G. Will, D. Fitzmaurice, D. Guha, A. Mondal and S. Mukherjee ; (1999) 'Spectrosopic Properties of 2-Hydroxypyridine and Excited State Anion Formation '. Indian Journal of Chemistry, 38A :753-759. [Details]
Waghorne, W.E. with: M. Meade, K. Hickey, Y. McCarthy, P.P Rastogi and M.C.R. Symons ; (1997) 'The Solvation of Some Non-Electrolytes in the Methanol + Acetonitrile Solvent System. A Combined Calorimetric and Spectroscopic Study'. Journal of the Chemical Society-Faraday Transactions, 93 :563-568. [Details]
Meade, M; Hickey, K; McCarthy, Y; Waghorne, WE; Symons, MR; Rastogi, PP; ; (1997) 'Solvation of solutes with S=O or C=O groups in the methanol-acetonitrile solvent system: A combined calorimetric and spectroscopic study'. Journal of the Chemical Society-Faraday Transactions, 93 (4):563-568. [Details]
Waghorne, W.E. with: M. Meade and M.C.R. Symons ; (1996) 'A Spectroscopic Study of the Solvation of Dimethylsulfoxide in Aqueous Acetonitrile and Acetone Solvent system'. Journal of the Chemical Society-Faraday Transactions, 92 :4395-4399. [Details]
Meade, M; Waghorne, WE; Symons, MCR; ; (1996) 'Spectroscopic study of the solvation of dimethyl sulfoxide in aqueous acetonitrile and acetone solvent systems'. Journal of the Chemical Society-Faraday Transactions, 92 (22):4395-4399. [Details]
HOGAN, P; MCSTRAVICK, I; MULLALLY, J; WAGHORNE, WE; ; (1994) 'ENTHALPIES OF TRANSFER OF TETRABUTYLAMMONIUM BROMIDE FROM WATER TO HIGHLY AQUEOUS WATER-METHANOL, WATER-ETHANOL, WATER-PROPAN-1-OL AND WATER-ACETONITRILE MIXTURES AT 298-K - CONSIDERATION OF THE EXTENDED COORDINATION MODEL SOLVATION PARAMETERS'. Journal of the Chemical Society-Faraday Transactions, 90 (18):2691-2695. [Details]
Waghorne, W.E. with: D. Feakins, F.M. Bates and K.G. Lawrence ; (1993) 'Relative Viscosities and Quasi-Thermodynamics of Solutions of TBA in the Methanol - Water System. A Different View of the Alkyl - Water Interaction'. Journal of the Chemical Society-Faraday Transactions, 89 :3381-3388. [Details]
Waghorne, W.E. with I.. McStravick, P. Hogan and J. Mullally ; (1993) 'Enthalpies of Transfer of Tetrabutylammonium Bromide from Water to Highly Aqueous Water + Methanol, Ethanol, Propan-1-ol and Acetonitrile Mixtures at 298K; Consideration of the Extended Coordination Model Solvation Parameters'. Journal of the Chemical Society-Faraday Transactions, 90 :2691-2695. [Details]
Waghorne, W.E. with: D. Feakins and J. Mullally ; (1993) 'Enthalpies of Transfer of Sodium and Potassium Chlorides from Water to Mixtures of Water with 1,4-Dioxan at 298K'. Journal of Solution Chemistry, 22 :311-319. [Details]
Waghorne, W.E.; (1993) 'Thermodynamics of Solvation in Mixed Solvents'. Chemical Society Reviews, :285-292. [Details]
Waghorne, W.E. with: D. Feakins, P. Hogan and C. O'Duinn ; (1992) 'Enthalpies of Transfer of Formamide, N-Methylformamide and N,N-Dimethylformamide from Water to Aqueous Acetonitrile at 298K'. Journal of the Chemical Society-Faraday Transactions, 88 :423-425. [Details]
Waghorne, W.E. with: G. Eaton, C. O'Duinn P.P. Rastogi and M.C.R. Symons ; (1992) 'Solvation of Some Amides in Mixed Solvent Systems. Comparison of the Results of Infra-Red Spectroscopic and Calorimetric Measurements'. Journal of the Chemical Society-Faraday Transactions, 88 :1137-1142. [Details]
Waghorne, W.E. with: D. Feakins and J. Mullally ; (1991) 'Enthalpies of Transfer of Tetrabutylammonium Bromide as Indicators of the Structure of Aqueous Solvents: Aqueous Methanol, Ethanol, Propan-1-ol, 2-Methylpropan-2-ol and 1,4-Dioxane Systems'. Journal of the Chemical Society-Faraday Transactions, 87 . [Details]
Waghorne, W.E. with: G. Carthy, D. Feakins and C. O'Duinn ; (1991) 'Enthalpies of Transfer of Formamide, N-Methylformamide, N,N-Dimethylformamide and Urea from Water to some Aqueous Alcohol Solvent Systems at 298K'. Journal of the Chemical Society-Faraday Transactions, 87 . [Details]
Waghorne, W.E. with: A. Costigan, D. Feakins, I. McStravick, C. O'Duinn and J. Ryan ; (1991) 'Enthalpies of Transfer of Some Non-electrolytes from Acetonitrile to Acetonitrile - Methanol Mixtures'. Journal of the Chemical Society-Faraday Transactions, 87 . [Details]
Waghorne, W.E. with: D. Feakins and J. Mullally ; (1990) 'Enthalpies of Transfer of 2-methylpropan-2-ol from Water to Mixtures of Water with Methanol, Ethanol and 1,4-Dioxan'. Journal of Solution Chemistry, 19 . [Details]
Waghorne, W.E. with: R.D. O'Neill, L.S. Sheiha and D. Feakins; (1990) 'A New Method for Determining Ionic Solvent Transport Numbers and Free Energy of Transfer of Electrolytes from Water to Mixed Aqueous Solvents'. Journal of the Chemical Society-Chemical Communications, :99-100. [Details]
Waghorne, W.E. with: D. Feakins, F.M. Canning and J.J Mullally ; (1989) 'The Thermodynamics of Solutions'. Pure Apllied Chemistry, 61 :133-142. [Details]
Waghorne, W.E. with: B.A. Fallon ; (1989) 'Free Energies of Transfer of Silver Bromide from Methanol to Methanol-Dimethylsulphoxide Mixtures at 298K'. Proceedings Royal Irish Academy, Section A, 89B :369-374. [Details]
Waghorne, W.E. with: D. Feakins and K.F. Johnson ; (1989) 'Thermodynamics of Ion Solvation in Mixed Aqueous Solvents. Part 3. Effect of Steric Hindrance to the Free energies of Transfer of Cations to 5 and 20% (w/w) Propan-1-ol-Water Mixtures '. Proceedings Royal Irish Academy, Section A, 89B :321-327. [Details]
Waghorne, W.E. with: K.C. Pillai and O. Wilson ; (1988) 'An Electrochemical Study of the Mercury/Lithium Perchlorate Interface in Dimethylsulphoxide - Propylene Carbonate Mixtures at 298K'. Journal of Electroanalytical Chemistry, 252 :151-168. [Details]
Waghorne, W.E. with; C. O'Duinn and D. Feakins ; (1987) 'Enthalpies of Transfer of Formamide, N-Methylformamide and N,N-Dimethylformamide from Methanol to Methanol + Dimethylsulphoxide Mixtures '. Journal of Solution Chemistry, 16 :907-915. [Details]
Waghorne, W.E. with: D.A. Brown, W.K. Glass and H.J. Toma ; (1987) 'Dithiocarbamates of Tungsten (III) and Tungsten (IV)'. Journal of the Chemical Society-Dalton Transactions, :2531-2536. [Details]
Waghorne, W.E. with D. Feakins, B.E. Hickey, M. Knox and P.J. McCarthy ; (1987) 'Correlations between the Transfer Thermodynamics of Simple Electrolytes and Structural Parameters, with Particular Reference to Steric Hindrance'. Journal of the Chemical Society-Chemical Communications, :611-613. [Details]
Waghorne, W.E. with: G. Carthy and D. Feakins ; (1987) 'Enthalpies of Transfer of Tetra-alkylammonium Halides from Water to Water-Propan-1-ol Mixtures at 25oC'. Journal of the Chemical Society-Faraday Transactions, 83 :2585-2592. [Details]
Waghorne, W.E.; (1986) 'The Viscosity and Structure of Solutions Part 1.-A New Theory of the Jones - Dole B-Coefficient and the Related Activation Parameters: Application to Aqueous Solutions'. Journal of the Chemical Society-Faraday Transactions, 82 :563-568. [Details]
Waghorne, W.E. with C. Cronnolly and K.C. Pillai ; (1986) 'Electrode Kinetic Studies of the Zn2+/Zn(Hg) and Li+/Li(Hg) Couples in Dimethylsulphoxide + Propylene Carbonate Solvent Systems'. Journal of Electroanalytical Chemistry, 207 :177-187. [Details]
Waghorne, W.E. with; J. Crudden, G.M. Delaney, D. Feakins, P.J. O'Reilly and K.G. Lawrence ; (1986) 'Viscosity and Structure of Solutions Part 2.-Measurement of the B-Coefficient for Alkali-metal Chlorides in Propan-1-ol - Water Mixtures at 25 and 35oC'. Journal of the Chemical Society-Faraday Transactions, 82 :2195-2206. [Details]
Waghorne, W.E. with: E. de Valera and D. Feakins ; (1985) 'Relationship between the Entropy of Transfer of a Solute and the Thermodynamic Functions of Mixed Solvents'. Journal of the Chemical Society-Faraday Transactions, 81 :2703-2710. [Details]
Waghorne, W.E. with: G. Carthy and D. Feakins ; (1984) 'Enthalpies of Transfer and Hydrophobic Solvation. Tetrabutylammonium Bromide in the Propan-1-ol + Water System'. Journal of the Chemical Society-Chemical Communications, :588-589. [Details]
Waghorne, W.E. with: B.G. Cox ; (1984) 'Free Energies, Enthalpies and Entropies of Transfer of Electrolytes from Propylene Carbonate to Dimethylsulphoxide + Propylene Carbonate Mixtures and from Methanol to Acetonitrile + Methanol Mixtures at 25oC '. Journal of the Chemical Society-Faraday Transactions, 80 :1267-1278. [Details]
Waghorne, W.E. with: D. Feakins and R. O'Neill ; (1983) 'Washburn Numbers Part 5.-Relative Solvent Transport Numbers for Ion Constituents in the Dioxan + Water and Dimethylsulphoxide + Water Systems'. Journal of the Chemical Society-Faraday Transactions, 79 :2289-2298. [Details]
Waghorne, W.E. with: E. de Valera and D. Feakins ; (1983) 'Relationship between the Enthalpy of Transfer of a Solute and the Thermodynamic Mixing Functions of the Mixed Solvent'. Journal of the Chemical Society-Faraday Transactions, 79 :1061-1071. [Details]
Waghorne, W.E. with: D. Feakins and R. O'Neill ; (1982) 'Preferential Solvation of Ions and Solvent Transport'. Pure Apllied Chemistry, 54 :2317-2326. [Details]
Waghorne, W.E. with: H. Rubalcava ; (1982) 'Infrared Spectroscopic Study of the Effects of Different Cations on N,N-Dimethylacetamide and Fully Deuterated N,N-Dimethylformamide '. Journal of the Chemical Society-Faraday Transactions, 78 :1199-1207. [Details]
Waghorne, W.E. with: D. Feakins, R. O'Neill and A.J.I. Ward ; (1982) 'Washburn Numbers Part 4.-The Erduy-Gruz Experiment. Relative Solvent Transport Numbers for Ion Constituents in Mixtures of Water with Raffinose, Glycine, Allyl Alcohol, Dimethylsulphoxide and Dioxan'. Journal of the Chemical Society-Faraday Transactions, B78 :1431-1449. [Details]
Waghorne, W.E. with: K.C. Pillai ; (1981) 'Electrical Double Layer Studies of Thiourea in Concentrated Potassium Chloride Solutions'. Journal of Electroanalytical Chemistry, 125 :487-489. [Details]
Waghorne, W.E. with: B.G. Cox ; (1980) 'Thermodynamics of Ion-Solvent Interactions'. Chemical Society Reviews, 9 :381-411. [Details]
Waghorne, W.E. with: D. Feakins and E. de Valera ; (1980) 'Studies in Ion Solvation in Non-Aqueous Solvents and their Aqueous Mixtures. Part 20.-Enthalpies of Transfer of Alkali-metal Halides in the Methanol + Water System from Enthalpies of Dilution'. Journal of the Chemical Society-Faraday Transactions, 76 :560-569. [Details]
Waghorne, W.E. with J.M. Clear, J. Corish, D. Feakins and H.W. Sidebottom ; (1980) 'A Comparitive Study of Photovoltaic Effects with Silver-Silver Halide Electrodes'. Berichte Der Bunsen-Gellschafte, 84 :634-642. [Details]
Waghorne, W.E. with: T.G. Clune, B.G.Cox and A.J.I. Ward ; (1980) 'Effect of Different Cations on the N-CO Rotational Barrier of N,N-Dimethylacetamide, Variable Temperature Proton Magnetic Resonance Study'. Journal of the Chemical Society-Faraday Transactions, 76 :1131-1137. [Details]
Waghorne, W.E. with: D. Feakins, R. O'Neill and A.J.I. Ward ; (1979) 'Relative Solvent Transport of Ion Constituents in Aqueous Organic Solvents'. Journal of the Chemical Society-Chemical Communications, :1029-1030. [Details]
Waghorne, W.E. with: B.G. Cox and R. Natarajan ; (1979) 'Thermodynamic Parameters for Transfer of Electrolytes from Water to Dimethylsulphoxide and to Dimethylsulphoxide + Water Mixtures'. Journal of the Chemical Society-Faraday Transactions, 75 :1780-1786. [Details]
Waghorne, W.E. with: B.G. Cox and C.K. Pigott ; (1979) 'Thermodynamic Parameters for Transfer of Cations from Propylene Carbonate to Dimethylsulphoxide and to Propylene Carbonate + Dimethylsulphoxide Mixtures '. Journal of the Chemical Society-Faraday Transactions, 75 :227-235. [Details]
Waghorne, W.E. with: B.G. Cox and R. Natarajan ; (1979) 'Thermodynamic Parameters for Transfer of Electrolytes from Water to Acetonitrile and to Acetonitrile + Water Mixtures '. Journal of the Chemical Society-Faraday Transactions, 75 :86-95. [Details]
Waghorne, W.E. with: A.J. Parker ; (1978) 'Solvation of Ions. XXVI Free Energies of Transfer of Ions to Multi-Site Solvents and Solvent Mixtures'. Australian Journal of Chemistry, 31 :1181-1187. [Details]
Waghorne, W.E. with: D. Feakins, E. de Valera, P.J. McCarthy and R. O'Neill ; (1978) 'Relative Solvent Transport of Ions in Binary Aqueous Mixtures: an Unambiguous Assignment to Ionic Constituents'. Journal of the Chemical Society-Chemical Communications, :218-219. [Details]
Waghorne, W.E. with: A.J. Parker, D.A. Clarke, R.A. Couche, G. Miller, and R.I. Tilley ; (1977) 'Solvation of Ions. Some Applications. III Solutions of Copper (I) Salts in Water Containing Ligands'. Australian Journal of Chemistry, 30 :1661-1672. [Details]
Waghorne, W.E. with: G. Clune and B.G. Cox ; (1976) 'Solvent Coordination and Free Energies of Transfer of Cations in Dipolar Aprotic Solvents'. Journal of the Chemical Society-Faraday Transactions, 72 :1294-1299. [Details]
Waghorne, W.E. with: D.M. Muir, A.J. Parker and J.H. Sharp ; (1975) 'Cuprous Hydrometallurgy. Part I. Electrorefining Copper via Acidic Solutions of Cuprous Sulphate Containing Organic Nitriles'. Hydrometallurgy, 1 :61-77. [Details]
Waghorne, W.E. with: D.M. Muir, A.J. Parker and J.H. Sharp ; (1975) 'Cuprous Hydrometallurgy. Part II. Electrowinning of Copper from Cuprous Sulphate Solutions Containing Organic Nitriles'. Hydrometallurgy, 1 :155-168. [Details]
Waghorne, W.E. with: B.G. Cox and A.J. Parker ; (1974) 'Coordination and Ionic Solvation'. Journal of Physical Chemistry, 78 :1731-1740. [Details]
Waghorne, W.E. with: R. Alexander, D.A. Owensby and A.J. Parker ; (1974) 'Solvation of Ions. XXII Solvation of Cations by N,N-Dimethylformamide and Soft N,N-Dimethylthioformamide'. Australian Journal of Chemistry, 27 :933-941. [Details]
Waghorne, W.E. with: B.G. Cox and A.J. Parker ; (1973) 'Liquid Junction Potentials between Electrolyte Solutions in Different Solvents'. Journal of American Chemical Society, 95 :1010-1014. [Details]
Waghorne, W.E. with :R. Alexander, A.J. Parker and J.H. Sharp ; (1972) 'Solvation of Ions XVI. Solvent Activity Coefficients of Single Ions. A Recommended Extrathermodynamic Assumption'. Journal of American Chemical Society, 94 :1148-1158. [Details]
                                                                                             

Research

Research Interests

The study of the interactions of solute molecules with the surrounding medium is one of the classic problems of physical chemistry. It has long been known that solvents exert a profound influence on chemical systems; recently the role of solvation in biological systems has been recognised, for example, the importance of hydrophobic interactions in processes such as protein folding. Our interests in solution chemistry include the study of the solvation of both electrolytes and non-electrolytes in aqueous, non-aqueous and mixed solvents. Our approach involves the application of a range of experimental techniques, in combination with solvation theories, to provide as complete a picture as possible of the solvation process. We are also involved in the measurement of solution properties with applications in areas such as the environmental impact of new solvents and process fluids. Current projects in this area include:
• the study of hydrophobic moieties by thermodynamic and spectroscopic techniques,
• the viscometric study non-electrolytes in mixed aqueous solvents
• spectroscopic studies of carbonyl containing solutes in mixed solvents
• measurement of uptake coefficients of environmentally significant organic compounds